{(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate
نویسنده
چکیده
In title complex, [Co(C(28)H(22)N(2)O(2))(C(5)H(5)N)(2)]ClO(4)·1.5H(2)O, the Co(III) ion is in a slightly distorted octa-hedral coordination environment with the pyridine ligands in a trans arrangement. In addition to the cation and anion, the asymmetric unit also contains three half-occupancy solvent water mol-ecules and all components are connected via inter-molecular O-H⋯O hydrogen bonds.
منابع مشابه
Diaqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ2 O,N,N′,O′}manganese(III) perchlorate 18-crown-6 hemisolvate monohydrate
In the cation of the title compound, [Mn(C(18)H(18)N(2)O(4))(H(2)O)(2)]ClO(4)·0.5C(12)H(24)O(6)·H(2)O, the Mn(III) ion is coordinated by two water O atoms, and two O atoms and two N atoms from the tetradentate 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]di-phenolate ligand, completing a distorted octa-hedral geometry. One O atom of the 18-crown-6-ether is disordered over two ...
متن کاملBis(4-chloropyridine){2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}cobalt(III) perchlorate methanol monosolvate
In the title complex, [Co(C(16)H(14)N(2)O(2))(C(5)H(4)ClN)(2)]ClO(4)·CH(3)OH, the Co(III) ion is in a slightly distorted octa-hedral CoN(4)O(2) coordination environment with the two 4-chloro-pyridine ligands in a trans arrangement.
متن کاملEthylenediammonium tetrakis({2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)) bis(perchlorate) dimethylformamide monosolvate
The title compound, (C(2)H(10)N(2))[Ni(C(16)H(14)N(2)O(2))](4)(ClO(4))(2)·C(3)H(7)NO, crystallizes with four Ni(salen) mol-ecules {salen is 2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate}, one ethyl-enediammonium cation (actually two half-cations, each located on a center of inversion), two perchlorate anions and one dimethyl-formamide solvent mol-ecule in the asymmetric unit. Each ...
متن کاملBis{μ-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}bis[(thiocyanato-κN)iron(III)]
The title compound, [Fe(2)(C(16)H(14)N(2)O(2))(2)(NCS)(2)], is isostructural with the Mn(III)-containing analogue. Each Fe(III) atom is chelated by a tetra-dentate 2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate ligand and by the N atom of a thio-cyanate anion, in a square-pyramidal arrangement. The complex mol-ecules form centrosymmetric dimers, with an Fe-O contact of 2.549 (3) Å, ...
متن کاملBis{μ-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}bis[(thiocyanato)manganese(III)]
The reported structure is a monoclinic polymorph of the title compound, [Mn(2)(C(16)H(14)N(2)O(2))(2)(NCS)(2)], which has been characterized previously in an ortho-rhom-bic form. Each Mn(III) atom is chelated by a tetra-dentate 2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate ligand and by the N atom of a thio-cyanate anion, in a square-pyramidal arrangement. The complexes form centro...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009